Lanthanide-Catalyzed Oxidative С–O Coupling of 1,3-Dicarbonyl Compounds with Diacyl Peroxides

Lanthanide-Catalyzed Oxidative С–O Coupling of 1,3-Dicarbonyl Compounds with Diacyl Peroxides Full article

Journal

Synlett
ISSN: 0936-5214 , E-ISSN: 1437-2096

Output data

Year: 2015, Volume: 26, Number: 06, Pages: 802-806 Pages count : 5 DOI: 10.1055/s-0034-1379982

Authors

Terent’ev Alexander O. ¹ , Vil Vera A. ¹ , Nikishin Gennady I. ¹ , Adam Waldemar ^2,3

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
2	Department of Chemistry, Facundo Bueso 110, University of Puerto Rico
3	Department of Chemistry, Facundo Bueso 110, University of Puerto Rico, Rio Piedras, Puerto Rico 00931, USA

The lanthanide-catalyzed oxidative C–O coupling of α-substituted 1,3-dicarbonyl compounds with diacyl peroxides (act both as oxidant and oxygen substituent) affords oxygen-functionalized adducts in up to 94% yield. The products of this convenient and efficient transformation serve as potentially valuable precursors for the synthesis of natural products and pharmaceuticals.

Terent’ev A.O. , Vil V.A. , Nikishin G.I. , Adam W.
Lanthanide-Catalyzed Oxidative С–O Coupling of 1,3-Dicarbonyl Compounds with Diacyl Peroxides
Synlett. 2015. V.26. N06. P.802-806. DOI: 10.1055/s-0034-1379982 WOS Scopus OpenAlex

≡ Web of science:	WOS:000351583700016
≡ Scopus:	2-s2.0-84925483414
≡ OpenAlex:	W2951345377