Incorporation of carbon dioxide into molecules of acetylene hydrocarbons on heterogeneous Ag-containing catalysts

Incorporation of carbon dioxide into molecules of acetylene hydrocarbons on heterogeneous Ag-containing catalysts Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2015, Volume: 64, Number: 12, Pages: 2796-2801 Pages count : 6 DOI: 10.1007/s11172-015-1228-4

Authors

Finashina E.D. ¹ , Tkachenko O.P. ¹ , Startseva A.Yu. ¹ , Krasovsky V.G. ¹ , Kustov L.M. ^1,2 , Beletskaya I.P. ²

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
2	Department of Chemistry, M. V. Lomonosov Moscow State University, Moscow, Russian Federation

The reaction between 2-(2-phenylethynyl)aniline and carbon dioxide on heterogeneous Ag-containing catalysts can lead either to benzoxazine-2-one or to 4-hydroxyquinoline-2(1Н)-one, depending on the reaction conditions (nature of the base, CO2 pressure). The structures of the products were confirmed by 1Н and 13С NMR spectroscopy. The maximum yield of the products (60 and 30% for benzoxazine-2-one and 4-hydroxyquinolin-2(1Н)-one, respectively) is achieved on the catalyst Ag(1%)/γ-Al2O3(F). According to the results of physicochemical studies, the high activity of the catalysts in the reactions proceeding via triple bond activation results from the combination of three factors. First, the catalyst contains metallic silver particles with the size >2 nm; second, metallic silver particles coexist with silver cations; and third, strong acid sites are present on the support surface.

Finashina E.D. , Tkachenko O.P. , Startseva A.Y. , Krasovsky V.G. , Kustov L.M. , Beletskaya I.P.
Incorporation of carbon dioxide into molecules of acetylene hydrocarbons on heterogeneous Ag-containing catalysts
Russian Chemical Bulletin. 2015. V.64. N12. P.2796-2801. DOI: 10.1007/s11172-015-1228-4 WOS Scopus OpenAlex

Web of science:	WOS:000383864900009
Scopus:	2-s2.0-84988354891
OpenAlex:	W2519858834

DB	Citing
OpenAlex	9
Scopus	9
Web of science	9