Chemical reactivity and solution structure: on the way to a paradigm shift? Обзор
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RSC Advances
ISSN: 2046-2069 |
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| Вых. Данные | Год: 2015, Том: 5, Номер: 58, Страницы: 46718-46734 Страниц : 17 DOI: 10.1039/c4ra17257d | ||
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Реферат:
Recent studies unveiled two unprecedented phenomena which together may induce a paradigm shift in understanding chemical reactivity in solutions which would no longer be related to molecular species. Research on chemical reactions under microfluidic conditions (and some other systems) revealed that the same compound involved in the same chemical reaction performed under slightly different conditions may exhibit a significantly altered chemical reactivity pattern (different chemical properties). This review aims at linking this discovery to another unusual finding that commonly used solutions are not homogeneous at the mesoscale suggesting that a solute, depending on concentration, solvent, temperature and the presence of other compounds including impurities, may exist in solutions as a variety of supramolecular species (supramers), which may also comprise solvent molecules, differing in size and structure, and hence physical and chemical properties.
Библиографическая ссылка:
Kononov L.O.
Chemical reactivity and solution structure: on the way to a paradigm shift?
RSC Advances. 2015. V.5. N58. P.46718-46734. DOI: 10.1039/c4ra17257d WOS Scopus OpenAlex
Chemical reactivity and solution structure: on the way to a paradigm shift?
RSC Advances. 2015. V.5. N58. P.46718-46734. DOI: 10.1039/c4ra17257d WOS Scopus OpenAlex
Идентификаторы БД:
| Web of science: | WOS:000355702900039 |
| Scopus: | 2-s2.0-84930958988 |
| OpenAlex: | W2165974964 |