Synthesis and photochromic properties of oxime derivatives of 2,3-diarylcyclopent-2-en-1-ones

Synthesis and photochromic properties of oxime derivatives of 2,3-diarylcyclopent-2-en-1-ones Full article

Journal

Photochemical & Photobiological Sciences
ISSN: 1474-9092 , E-ISSN: 1474-905X

Output data

Year: 2013, Volume: 12, Number: 9, Pages: 1717-1725 Pages count : 9 DOI: 10.1039/c3pp50055a

Authors

Shirinian Valerii Z. ¹ , Lonshakov Dmitry V. ¹ , Lvov Andrey G. ¹ , Shimkin Alexey A. ² , Krayushkin Mikhail M. ¹

Affiliations

1	N.D. Zelinsky Institute of Organic Chemistry RAS, 47, Leninsky prosp., 119991, Moscow, Russian Federation
2	All-Russian Scientific Research Institute of Aviation Materials, 17, Radio Street, Moscow, 105005, Russian Federation

A wide range of new oxime-based photochromic diarylethenes of the cyclopentenone series have been synthesized. Their spectral properties have been investigated in detail upon UV/vis light irradiation in acetonitrile solution, and distinct correlations between photochromic characteristics and substance structures are revealed. It was found that the introduction of an oxime group into the cyclopentene ring has a significant influence on the switching characteristics—primarily on the thermal stability, and a series of thermally stable oxime-based photochromic diarylcyclopentenones have been prepared. The results obtained suggest that the modifications of the ethene “bridge” are a promising way to tune the spectral parameters of diarylethenes in an accurate manner and thus to synthesize the photochromic compounds with desired properties.

Shirinian V.Z. , Lonshakov D.V. , Lvov A.G. , Shimkin A.A. , Krayushkin M.M.
Synthesis and photochromic properties of oxime derivatives of 2,3-diarylcyclopent-2-en-1-ones
Photochemical & Photobiological Sciences. 2013. V.12. N9. P.1717-1725. DOI: 10.1039/c3pp50055a WOS Scopus OpenAlex

Web of science:	WOS:000323174000017
Scopus:	2-s2.0-84882426098
OpenAlex:	W1998694796

DB	Citing
OpenAlex	24
Scopus	24
Web of science	24