A practical anodic oxidation of aminofurazans to azofurazans: an environmentally friendly route

A practical anodic oxidation of aminofurazans to azofurazans: an environmentally friendly route Full article

Journal

RSC Advances
ISSN: 2046-2069

Output data

Year: 2015, Volume: 5, Number: 47, Pages: 37617-37625 Pages count : 9 DOI: 10.1039/c5ra05726d

Authors

Sheremetev Aleksei B. ¹ , Lyalin Boris V. ¹ , Kozeev Andrei M. ¹ , Palysaeva Nadezhda V. ¹ , Struchkova Marina I. ¹ , Suponitsky Kyrill Yu. ²

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
2	A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991 Moscow, Russian Federation

Nickel oxyhydroxide, NiOOH, anode has been shown to be an effective tool for the oxidation of aminofurazans to azofurazans in ca. 1% aqueous alkali at room temperature. The electrochemical reaction is simple and convenient, eliminating the use of expensive and toxic organic or inorganic oxidants. The green economic preparation of desired azo compounds is very clean, producing only H2 as a result of cathodic reduction.

Sheremetev A.B. , Lyalin B.V. , Kozeev A.M. , Palysaeva N.V. , Struchkova M.I. , Suponitsky K.Y.
A practical anodic oxidation of aminofurazans to azofurazans: an environmentally friendly route
RSC Advances. 2015. V.5. N47. P.37617-37625. DOI: 10.1039/c5ra05726d WOS Scopus OpenAlex

≡ Web of science:	WOS:000353653200057
≡ Scopus:	2-s2.0-84929484258
≡ OpenAlex:	W1909641936