Generation of oxodiazonium ions 4. Nitramine O-alkyl derivatives in the synthesis of benzotetrazine-1,3-dioxides Научная публикация
| Журнал |
Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285 |
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| Вых. Данные | Год: 2011, Том: 60, Номер: 10, Страницы: 2051-2056 Страниц : 6 DOI: 10.1007/s11172-011-0312-7 | ||
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Реферат:
A new method for the synthesis of benzotetrazine-1,3-dioxides was developed from the 2-(tert-butyl-NNO-azoxy)-N-nitroaniline O-alkyl derivatives upon the action of strong acids (H2SO4, MeSO3H, CF3CO2H) or BF3·Et2O. A mechanism suggested for these reactions includes transformation of the N=N(O)OR group (R = Me, Pri) to the oxodiazonium ion (N=N=O)+, which intramolecularly reacts with the neighboring tert-butyl-NNO-azoxy group, furnishing the tetrazine-1,3-dioxide ring.
Библиографическая ссылка:
Klenov M.S.
, Churakov A.M.
, Strelenko Y.A.
, Tartakovsky V.A.
Generation of oxodiazonium ions 4. Nitramine O-alkyl derivatives in the synthesis of benzotetrazine-1,3-dioxides
Russian Chemical Bulletin. 2011. V.60. N10. P.2051-2056. DOI: 10.1007/s11172-011-0312-7 WOS Scopus OpenAlex
Generation of oxodiazonium ions 4. Nitramine O-alkyl derivatives in the synthesis of benzotetrazine-1,3-dioxides
Russian Chemical Bulletin. 2011. V.60. N10. P.2051-2056. DOI: 10.1007/s11172-011-0312-7 WOS Scopus OpenAlex
Идентификаторы БД:
| ≡ Web of science: | WOS:000305679700015 |
| ≡ Scopus: | 2-s2.0-84864560798 |
| ≡ OpenAlex: | W1998450401 |