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Electrochemical oxidation of tetracycline on a boron doped diamond electrode within the stability potentials of water Full article

Journal Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285
Output data Year: 2013, Volume: 62, Number: 12, Pages: 2590-2594 Pages count : 5 DOI: 10.1007/s11172-013-0377-6
Authors Borisova D.A. 1 , Vedenyapina M.D. 1,2 , Krylova I.V. 1 , Rakishev A.K. 1 , Weichgrebe D. 3 , Stopp P. 3 , Rosenwinkel K.-H. 3 , Vedenyapin A.A. 1
Affiliations
1 N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation
2 Moscow Technological Institute “VTU”, 38a Leninsky prosp., 119334, Moscow, Russian Federation
3 Institute of Sanitary Engineering and Waste Management, Leibniz University of Hannover, 1 Welfengarten, D-30167, Hannover, Germany

Abstract: Electrochemical oxidation of tetracycline on a boron doped diamond electrode within the stability potentials of water was studied in order to develop an approach for the purification of waste water containing medicinal agents. Cyclic voltammetry, HPLC, and high resolution mass spectrometry were used to establish that in the electrochemical oxidation process, tetracycline adds one oxygen atom to further form organic compounds with molecular weights higher than that of tetracycline. It was found that tetracycline in this region of potentials can be almost completely deactivated without its mineralization.
Cite: Borisova D.A. , Vedenyapina M.D. , Krylova I.V. , Rakishev A.K. , Weichgrebe D. , Stopp P. , Rosenwinkel K.-H. , Vedenyapin A.A.
Electrochemical oxidation of tetracycline on a boron doped diamond electrode within the stability potentials of water
Russian Chemical Bulletin. 2013. V.62. N12. P.2590-2594. DOI: 10.1007/s11172-013-0377-6 WOS Scopus OpenAlex
Identifiers:
≡ Web of science: WOS:000339730300005
≡ Scopus: 2-s2.0-84905179527
≡ OpenAlex: W2088319519
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