Tsuji–Trost allylation of CH acids in supercritical carbon dioxide: advantages and problems

Tsuji–Trost allylation of CH acids in supercritical carbon dioxide: advantages and problems Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2013, Volume: 23, Number: 2, Pages: 84-85 Pages count : 2 DOI: 10.1016/j.mencom.2013.03.009

Authors

Vasil’ev Andrei A. ¹ , Kuchurov Ilya V. ¹ , Zlotin Sergei G. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation

The Pd(PPh3)4-catalyzed reaction between a-cyano or b-oxo carboxylates and allyl acetate in supercritical carbon dioxide with the K2CO3–18-crown-6 system as a base affords exhaustive allylation products in high yields, whereas malononitrile and acetylacetone of higher CH acidity form the mixtures of mono- and diallylated derivatives in moderate yields.

Vasil’ev A.A. , Kuchurov I.V. , Zlotin S.G.
Tsuji–Trost allylation of CH acids in supercritical carbon dioxide: advantages and problems
Mendeleev Communications. 2013. V.23. N2. P.84-85. DOI: 10.1016/j.mencom.2013.03.009 Scopus OpenAlex

Scopus:	2-s2.0-84875172379
OpenAlex:	W2952355812

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