Photocatalytic reduction of fluoroalkyl-substituted alcohols activated by pentafluoropyridine

Photocatalytic reduction of fluoroalkyl-substituted alcohols activated by pentafluoropyridine Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2023, Volume: 33, Number: 3, Pages: 387-389 Pages count : 3 DOI: 10.1016/j.mencom.2023.04.028

Authors

Lunkov Sergey S. ^1,2 , Zemtsov Artem A. ² , Levin Vitalij V. ² , Dilman Alexander D. ²

Affiliations

1	Department of Chemistry, M. V. Lomonosov Moscow State University, 119991 Moscow, Russian Federation
2	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation

A new method for deoxygenation of fluoroalkyl-substituted alcohols involves derivatization of the hydroxy group with pentafluoropyridine followed by photoredox catalyzed reduction of the obtained hetaryl ethers using γ-terpinene as a source of hydrogen. The initial alcohols can be easily obtained by nucleophilic fluoroalkylation of the corresponding aldehydes.

Lunkov S.S. , Zemtsov A.A. , Levin V.V. , Dilman A.D.
Photocatalytic reduction of fluoroalkyl-substituted alcohols activated by pentafluoropyridine
Mendeleev Communications. 2023. V.33. N3. P.387-389. DOI: 10.1016/j.mencom.2023.04.028 WOS Scopus OpenAlex

Web of science:	WOS:001010903800001
Scopus:	2-s2.0-85159574517
OpenAlex:	W4377016191

DB	Citing
OpenAlex	2
Scopus	3
Web of science	2