Enantioselective addition of carbon acids to α-nitroalkenes: the first asymmetric aminocatalytic reaction in liquefied carbon dioxide

Enantioselective addition of carbon acids to α-nitroalkenes: the first asymmetric aminocatalytic reaction in liquefied carbon dioxide Full article

Journal

Tetrahedron Letters
ISSN: 0040-4039 , E-ISSN: 1873-3581

Output data

Year: 2012, Volume: 53, Number: 27, Pages: 3502-3505 Pages count : 4 DOI: 10.1016/j.tetlet.2012.04.123

Authors

Nigmatov A.G. ¹ , Kuchurov I.V. ¹ , Siyutkin D.E. ¹ , Zlotin S.G. ¹

Affiliations

1	N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation

Carbon acids, in particular malonates, malononitrile, and anthranone, react enantioselectively with α-nitroalkenes in the presence of Takemoto’s organocatalyst in liquid carbon dioxide medium (100 bar, rt), under homogeneous conditions, to afford the corresponding Michael adducts in moderate to high yields and with enantioselectivities comparable with those obtained in organic solvents.

Nigmatov A.G. , Kuchurov I.V. , Siyutkin D.E. , Zlotin S.G.
Enantioselective addition of carbon acids to α-nitroalkenes: the first asymmetric aminocatalytic reaction in liquefied carbon dioxide
Tetrahedron Letters. 2012. V.53. N27. P.3502-3505. DOI: 10.1016/j.tetlet.2012.04.123 Scopus OpenAlex

Scopus:	2-s2.0-84861644323
OpenAlex:	W2098278542

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