Nitropyrazoles 20. Synthesis and transformations of 1-methoxymethyl-3,4,5-trinitropyrazole

Nitropyrazoles 20. Synthesis and transformations of 1-methoxymethyl-3,4,5-trinitropyrazole Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2012, Volume: 61, Number: 2, Pages: 464-466 Pages count : 3 DOI: 10.1007/s11172-012-0065-y

Authors

Dalinger I.L. ¹ , Vatsadze I.A. ¹ , Shkineva T.K. ¹ , Popova G.P. ¹ , Shevelev S.A. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

1-Methoxymethyl-3,4,5-trinitropyrazole, synthesized from 3,4,5-trinitropyrazole by the action of methoxymethyl chloride, was involved into the nucleophilic substitution reaction with N-nucleophiles (aliphatic amines, hydrazine derivatives). The reaction was effected regioselectively with substitution of the nitro group at position 5 in good yields. The thus obtained 5-R-substituted compounds under acid hydrolysis conditions give N-unsubstituted 5-R-3,4-dinitropyrazoles.

Dalinger I.L. , Vatsadze I.A. , Shkineva T.K. , Popova G.P. , Shevelev S.A.
Nitropyrazoles 20. Synthesis and transformations of 1-methoxymethyl-3,4,5-trinitropyrazole
Russian Chemical Bulletin. 2012. V.61. N2. P.464-466. DOI: 10.1007/s11172-012-0065-y WOS Scopus OpenAlex

≡ Web of science:	WOS:000312068000034
≡ Scopus:	2-s2.0-84877061150
≡ OpenAlex:	W2106760877