Trapping of Difluorocarbene by Frustrated Lewis Pairs

Trapping of Difluorocarbene by Frustrated Lewis Pairs Full article

Journal

Angewandte Chemie International Edition
ISSN: 1433-7851 , E-ISSN: 1521-3773

Output data

Year: 2020, Volume: 59, Number: 30, Pages: 12428-12431 Pages count : 4 DOI: 10.1002/anie.202001354

Authors

Smirnov Vladimir O. ¹ , Volodin Alexander D. ² , Korlyukov Alexander A. ^2,3 , Dilman Alexander D. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry 119991 Moscow Leninsky prosp. 47 Russian Federation
2	A. N. Nesmeyanov Institute of Organoelement Compounds 119991 Moscow Vavilov str. 28 Russian Federation
3	N. I. Pirogov Russian National Research Medical University Ostrovitianov str., 1 117997 Moscow Russian Federation

Frustrated Lewis pairs consisting of diphenylphosphino and boryl groups located at the ortho-position can trap difluorocarbene affording stable zwitterionic adducts. The reaction can be reversed to release difluorocarbene at elevated temperatures.

Smirnov V.O. , Volodin A.D. , Korlyukov A.A. , Dilman A.D.
Trapping of Difluorocarbene by Frustrated Lewis Pairs
Angewandte Chemie International Edition. 2020. V.59. N30. P.12428-12431. DOI: 10.1002/anie.202001354 WOS Scopus OpenAlex

Web of science:	WOS:000521623700001
Scopus:	2-s2.0-85082936799
OpenAlex:	W3010966446

DB	Citing
OpenAlex	52
Scopus	38
Web of science	47