Synthesis of quinolizin-2-one and pyrido[1,2-a]azepin-2-one derivatives from difluoroboron complexes of aroylacetones and O-methyllactims

Synthesis of quinolizin-2-one and pyrido[1,2-a]azepin-2-one derivatives from difluoroboron complexes of aroylacetones and O-methyllactims Научная публикация

Журнал

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Вых. Данные

Год: 2011, Том: 60, Номер: 10, Страницы: 2027-2029 Страниц : 3 DOI: 10.1007/s11172-011-0308-3

Авторы

Kravtsov I.V. ¹ , Baranin S.V. ¹ , Belyakov P.A. ¹ , Dorokhov V.A. ¹

Организации

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

O-Methyllactims react at the methyl group of difluoroboron complexes of aroylacetones with the formation of condensation products, novel difluoroboron chelates of 1-aryl-4-(piperi-din-2-ylidene)butane-1,3-diones and 1-aryl-4-(azepan-2-ylidene)butane-1,3-diones, which upon the action of concentrated HCl in ethanol are transformed into the corresponding quino-lizin-2-one and pyrido[1,2-a]azepin-2-one derivatives.

Kravtsov I.V. , Baranin S.V. , Belyakov P.A. , Dorokhov V.A.
Synthesis of quinolizin-2-one and pyrido[1,2-a]azepin-2-one derivatives from difluoroboron complexes of aroylacetones and O-methyllactims
Russian Chemical Bulletin. 2011. V.60. N10. P.2027-2029. DOI: 10.1007/s11172-011-0308-3 WOS Scopus OpenAlex

≡ Web of science:	WOS:000305679700011
≡ Scopus:	2-s2.0-84864540674
≡ OpenAlex:	W1974475596