Regioselectivity of styrene carbonylation in the presence of palladium(II) complexes

Regioselectivity of styrene carbonylation in the presence of palladium(II) complexes Научная публикация

Журнал

Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X

Вых. Данные

Год: 2011, Том: 85, Номер: 5, Страницы: 786-789 Страниц : 4 DOI: 10.1134/s0036024411050207

Авторы

Lapidus A.L. ¹ , Eliseev O.L. ¹ , Zvyagintsev N.V. ² , Kondrat’ev L.T. ^1,2

Организации

1	Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, Moscow, 119991, Russia
2	Russian State University of Tourism and Service, Moscow, Russia

The influence of a catalyst on regioselectivity of styrene carbonylation in ionic liquids catalyzed by palladium(II) complexes was studied. The mechanism of the migration insertion of styrene at the palladium-hydrogen bond determining the regioselectrivity of the whole reaction, which is treated as electrophilic addition to the multiple bond of styrene, was studied. A study of the structure of intermediate complexes formed at this stage was performed using the B3LYP method of density functional theory.

Lapidus A.L. , Eliseev O.L. , Zvyagintsev N.V. , Kondrat’ev L.T.
Regioselectivity of styrene carbonylation in the presence of palladium(II) complexes
Russian Journal of Physical Chemistry A. 2011. V.85. N5. P.786-789. DOI: 10.1134/s0036024411050207 WOS Scopus OpenAlex

Web of science:	WOS:000289292400010
Scopus:	2-s2.0-79955831563
OpenAlex:	W1982812495

БД	Цитирований
OpenAlex	2
Scopus	2
Web of science	3