Octaorgano Silsesquioxanes with Encapsulated Fluoride Anion, TBA(F-@T8),as a New Class of Non-Coordinating Non-Nucleophilic Supporting Electrolytes Научная публикация
| Журнал |
ECS transactions
ISSN: 2151-2051 , E-ISSN: 1938-5862 |
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| Вых. Данные | Год: 2013, Том: 45, Номер: 30, Страницы: 29-38 Страниц : 10 DOI: 10.1149/04530.0029ecst | ||||||
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Реферат:
The negative charge of F- encapsulated inside the silsesquioxane cage of F-@T8R8 anions is unavailable for external nucleophiles, which makes these systems suitable for stabilization of electrophilic species (carbocations, silicenium cations, Lewis acids etc). Potentially useful for electrochemistry salts (R: Ph, CH2CN, CH2CH2CN, CH2CH2CF3) with tetrabutylammonium cations were prepared from triethoxyorganosilanes RSi(OEt)3 whose R σ Ph. Anodic potentials with these salts are limited by oxidation of R groups (Elim ≅ ° 2 V vs SCE). Their conductivity in THF and AN is comparable to that of conventional TBA salts. Low nucleophilicity of F-@T8R8 anions allowed to stabilize electrophilic species formed by oxidation of 1,1,2,2-tetramethyl-1,2-bis(quinolin-8-yloxy)disilane, not observed in conventional systems CH3CN/ TBAPF6 or CH2Cl2/TBAPF6. These non-coordinating and non-nucleophilic anions can be used in THF, DME and liquid SO2, they are suitable for EPR-spectroelectrochemistry and are expected to find applications in anodic electrochemistry along with perfluoro arylborates and carborane anions.
Библиографическая ссылка:
Syroeshkin M.
, Wang Y.
, Dieng M.
, Gul'tyai V.
, Jouikov V.
Octaorgano Silsesquioxanes with Encapsulated Fluoride Anion, TBA(F-@T8),as a New Class of Non-Coordinating Non-Nucleophilic Supporting Electrolytes
ECS transactions. 2013. V.45. N30. P.29-38. DOI: 10.1149/04530.0029ecst Scopus OpenAlex
Octaorgano Silsesquioxanes with Encapsulated Fluoride Anion, TBA(F-@T8),as a New Class of Non-Coordinating Non-Nucleophilic Supporting Electrolytes
ECS transactions. 2013. V.45. N30. P.29-38. DOI: 10.1149/04530.0029ecst Scopus OpenAlex
Идентификаторы БД:
| Scopus: | 2-s2.0-84885746445 |
| OpenAlex: | W1986172879 |