Synthesis of Cyclic Peroxides Containing the Si-gem-bisperoxide Fragment. 1,2,4,5,7,8-Hexaoxa-3-silonanes as a New Class of Peroxides

Synthesis of Cyclic Peroxides Containing the Si-gem-bisperoxide Fragment. 1,2,4,5,7,8-Hexaoxa-3-silonanes as a New Class of Peroxides Full article

Journal

Journal of Organic Chemistry
ISSN: 1520-6904 , E-ISSN: 0022-3263

Output data

Year: 2008, Volume: 73, Number: 8, Pages: 3169-3174 Pages count : 6 DOI: 10.1021/jo7027213

Authors

Terent'ev Alexander O. ¹ , Platonov Maxim M. ¹ , Tursina Anna I. ² , Chernyshev Vladimir V. ^2,3 , Nikishin Gennady I. ¹

Affiliations

1	N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation
2	Department of Chemistry, Moscow State University, 119992 Moscow, Russian Federation
3	A.N. Frumkin Institute of Physical Chemistry and Electrochemistry, 31 Leninsky prosp., 119991

A method was developed for the synthesis of the previously unknown class of organic peroxides, 1,2,4,5,7,8-hexaoxa-3-silonanes, based on the reaction of dialkyldichlorosilanes with 1,1‘-dihydroperoxyperoxides. 1,2,4,5,7,8-Hexaoxa-3-silonanes are rather stable under ambient conditions and were characterized by NMR spectroscopy, X-ray diffraction, and elemental analysis. Their yields are in a range of 59−96%. The attempts were made to prepare 1,2,4,5-tetraoxa-3-silinanes by the reaction of dialkyldichlorosilanes with gem-bishydroperoxides. 1,2,4,5-Tetraoxa-3-silinanes were detected by NMR spectroscopy; these compounds rapidly decompose upon isolation.

Terent'ev A.O. , Platonov M.M. , Tursina A.I. , Chernyshev V.V. , Nikishin G.I.
Synthesis of Cyclic Peroxides Containing the Si-gem-bisperoxide Fragment. 1,2,4,5,7,8-Hexaoxa-3-silonanes as a New Class of Peroxides
Journal of Organic Chemistry. 2008. V.73. N8. P.3169-3174. DOI: 10.1021/jo7027213 WOS Scopus OpenAlex

≡ Web of science:	WOS:000254883700022
≡ Scopus:	2-s2.0-42149143025
≡ OpenAlex:	W2019237192