Oxidation of cycloalkanones with hydrogen peroxide: an alternative route to the Baeyer–Villiger reaction. Synthesis of dicarboxylic acid esters Научная публикация
| Журнал |
Tetrahedron
ISSN: 0040-4020 , E-ISSN: 1464-5416 |
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| Вых. Данные | Год: 2008, Том: 64, Номер: 34, Страницы: 7944-7948 Страниц : 5 DOI: 10.1016/j.tet.2008.06.027 | ||
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Реферат:
The acid-catalyzed oxidation of cycloalkanones C5–C8 and C12 with hydrogen peroxide in alcohols was performed, and dicarboxylic acid esters were obtained as the major products in 53–70% yields. In the first step, geminal bishydroperoxides are generated from five-to-seven-membered cyclic ketones. The Baeyer–Villiger reaction is a side process accompanied by the formation of ω-hydroxycarboxylic acid esters.
Библиографическая ссылка:
Terent'ev A.O.
, Platonov M.M.
, Kashin A.S.
, Nikishin G.I.
Oxidation of cycloalkanones with hydrogen peroxide: an alternative route to the Baeyer–Villiger reaction. Synthesis of dicarboxylic acid esters
Tetrahedron. 2008. V.64. N34. P.7944-7948. DOI: 10.1016/j.tet.2008.06.027 WOS Scopus OpenAlex
Oxidation of cycloalkanones with hydrogen peroxide: an alternative route to the Baeyer–Villiger reaction. Synthesis of dicarboxylic acid esters
Tetrahedron. 2008. V.64. N34. P.7944-7948. DOI: 10.1016/j.tet.2008.06.027 WOS Scopus OpenAlex
Идентификаторы БД:
| ≡ Web of science: | WOS:000258271300012 |
| ≡ Scopus: | 2-s2.0-46649089897 |
| ≡ OpenAlex: | W1980759477 |