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The specific reactivity of 3,4,5-trinitro-1H-pyrazole Full article

Journal Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436
Output data Year: 2010, Volume: 20, Number: 5, Pages: 253-254 Pages count : 2 DOI: 10.1016/j.mencom.2010.09.003
Authors Dalinger Igor L. 1 , Vatsadze Irina A. 1 , Shkineva Tatyana K. 1 , Popova Galina P. 1 , Shevelev Svyatoslav A. 1
Affiliations
1 N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation

Abstract: Nitration of 3,5-dinitropyrazole with HNO3–H2SO4 mixture gives 3,4,5-trinitro-1H-pyrazole, which in reaction with ammonia, amines or thiols under mild conditions undergoes regioselective nucleophilic substitution of the 4-positioned nitro group.
Cite: Dalinger I.L. , Vatsadze I.A. , Shkineva T.K. , Popova G.P. , Shevelev S.A.
The specific reactivity of 3,4,5-trinitro-1H-pyrazole
Mendeleev Communications. 2010. V.20. N5. P.253-254. DOI: 10.1016/j.mencom.2010.09.003 WOS Scopus OpenAlex
Identifiers:
≡ Web of science: WOS:000283695500003
≡ Scopus: 2-s2.0-77958043041
≡ OpenAlex: W2952768027
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