Photocatalytic Atom‐Transfer Radical Addition of Activated Chlorides to Alkenes

Photocatalytic Atom‐Transfer Radical Addition of Activated Chlorides to Alkenes Full article

Journal

Advanced Synthesis & Catalysis
ISSN: 1615-4169 , E-ISSN: 1615-4150

Output data

Year: 2021, Volume: 363, Number: 23, Pages: 5336-5340 Pages count : 5 DOI: 10.1002/adsc.202101047

Authors

Kostromitin Vladislav S. ^1,2 , Zemtsov Artem A. ¹ , Levin Vitalij V. ¹ , Dilman Alexander D. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, 119991 Moscow, Leninsky prosp. 47, Russian Federation
2	Lomonosov Moscow State University Department of Chemistry 119991 Moscow Leninskie Gory 1–3 Russian Federation

A protocol for performing atom transfer radical addition of activated alkyl chlorides to alkenes is described. The reaction is promoted by blue light in the presence of an organic photocatalyst (3DPA2FBN), serving to generate free radicals, and a copper complex (IMesCuCl), which facilitates the chlorine transfer step. The reaction works efficiently with fluorinated and non-fluorinated α-chloroesters.

Kostromitin V.S. , Zemtsov A.A. , Levin V.V. , Dilman A.D.
Photocatalytic Atom‐Transfer Radical Addition of Activated Chlorides to Alkenes
Advanced Synthesis & Catalysis. 2021. V.363. N23. P.5336-5340. DOI: 10.1002/adsc.202101047 WOS Scopus OpenAlex

Web of science:	WOS:000711232300001
Scopus:	2-s2.0-85118221722
OpenAlex:	W3206169456

DB	Citing
OpenAlex	17
Scopus	12
Web of science	15