HNO2-Assisted Triazine Cycle Contraction in 3-oxo-,3-thioxo- and 3-imino-5,7-dimethyl-4a,7a-diphenyl-perhydroimidazo[4,5-e][1,2,4]triazin-6-ones

HNO2-Assisted Triazine Cycle Contraction in 3-oxo-,3-thioxo- and 3-imino-5,7-dimethyl-4a,7a-diphenyl-perhydroimidazo[4,5-e][1,2,4]triazin-6-ones Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2012, Volume: 22, Number: 6, Pages: 299-301 Pages count : 3 DOI: 10.1016/j.mencom.2012.11.006

Authors

Kravchenko Angelina N. ¹ , Gazieva Galina A. ¹ , Vasilevskii Sergei V. ¹ , Belyakov Pavel A. ¹ , Nelyubina Yulia V. ²

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
2	A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991 Moscow, Russian Federation

Treatment of 3-oxo-, 3-thioxo- and 3-imino-5,7-dimethyl-4a,7a-diphenylperhydroimidazo[4,5-e][1,2,4]triazin-6-ones with NaNO2 in the presence of AcOH caused contraction of the perhydrotriazine cycle to the imidazolidine one. The products were transformed into glycolurils and their analogues.

Kravchenko A.N. , Gazieva G.A. , Vasilevskii S.V. , Belyakov P.A. , Nelyubina Y.V.
HNO2-Assisted Triazine Cycle Contraction in 3-oxo-,3-thioxo- and 3-imino-5,7-dimethyl-4a,7a-diphenyl-perhydroimidazo[4,5-e][1,2,4]triazin-6-ones
Mendeleev Communications. 2012. V.22. N6. P.299-301. DOI: 10.1016/j.mencom.2012.11.006 WOS Scopus OpenAlex

≡ Web of science:	WOS:000312919100006
≡ Scopus:	2-s2.0-84870312016
≡ OpenAlex:	W2953294706