Electrochemically induced aldol reaction of cyclic 1,3-diketones with isatins

Electrochemically induced aldol reaction of cyclic 1,3-diketones with isatins Full article

Journal

Electrochimica Acta
ISSN: 1873-3859 , E-ISSN: 0013-4686

Output data

Year: 2010, Volume: 55, Number: 6, Pages: 2129-2133 Pages count : 5 DOI: 10.1016/j.electacta.2009.11.045

Authors

Elinson Michail N. ¹ , Merkulova Valentina M. ¹ , Ilovaisky Alexey I. ¹ , Chizhov Alexander O. ¹ , Belyakov Pavel A. ¹ , Barba Fructuoso ² , Batanero Belen ²

Affiliations

1	N.D. Zelinsky Institute of Organic Chemistry, Leninsky prospect 47, 119991 Moscow, Russia
2	Department of Organic Chemistry, University of Alcalá, 28871 Alcalá de Henares, Madrid, Spain

The electrolysis of isatins and cyclic 1,3-diketones in alcohol in an undivided cell results in the formation of the previously unknown substituted 2-(3-hydroxy-2-oxo-2,3-dihydro-1H-indol-3-yl)cyclohexane-1,3-diones in 70–85% substance yields and 700–850% current efficiency. Thus, the simple electrocatalytic system can produce, under mild conditions the new electrochemically induced aldol reaction of isatins and cyclic 1,3-diketones.

Elinson M.N. , Merkulova V.M. , Ilovaisky A.I. , Chizhov A.O. , Belyakov P.A. , Barba F. , Batanero B.
Electrochemically induced aldol reaction of cyclic 1,3-diketones with isatins
Electrochimica Acta. 2010. V.55. N6. P.2129-2133. DOI: 10.1016/j.electacta.2009.11.045 WOS Scopus OpenAlex

Web of science:	WOS:000275363900037
Scopus:	2-s2.0-75349094889
OpenAlex:	W1974030669

DB	Citing
OpenAlex	19
Scopus	21
Web of science	22