Pd-catalyzed allylic amination in supercritical carbon dioxide: Synthesis of carborane-containing terpenoids

Pd-catalyzed allylic amination in supercritical carbon dioxide: Synthesis of carborane-containing terpenoids Full article

Journal

Journal of Supercritical Fluids
ISSN: 1872-8162 , E-ISSN: 0896-8446

Output data

Year: 2010, Volume: 54, Number: 2, Pages: 218-221 Pages count : 4 DOI: 10.1016/j.supflu.2010.04.010

Authors

Lyubimov Sergey E. ¹ , Kuchurov Ilya V. ² , Verbitskaya Tatiana A. ¹ , Rastorguev Eugenie A. ¹ , Kalinin Valery N. ¹ , Zlotin Sergei G. ² , Davankov Vadim A. ¹

Affiliations

1	A. N. Nesmeyanov-Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov Street 28, 119991 Moscow, Russia
2	N. D. Zelinsky-Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prosp. 47, 119991 Moscow, Russia

Pd-catalyzed amination of allylic carbonates with N-(ortho-carboran-3-yl)-N-methylamine was carried out in supercritical CO2. It has been demonstrated that complete conversion of allylic carbonates to the corresponding carborane amines with excellent regioselectivity may be achieved in scCO2 (170 atm, 60 °C) using NaHCO3 as the acceptor base. The reaction offers a selective method for the preparation of allylic amines and provides a useful approach to new terpenoids.

Lyubimov S.E. , Kuchurov I.V. , Verbitskaya T.A. , Rastorguev E.A. , Kalinin V.N. , Zlotin S.G. , Davankov V.A.
Pd-catalyzed allylic amination in supercritical carbon dioxide: Synthesis of carborane-containing terpenoids
Journal of Supercritical Fluids. 2010. V.54. N2. P.218-221. DOI: 10.1016/j.supflu.2010.04.010 Scopus OpenAlex

Scopus:	2-s2.0-77955304415
OpenAlex:	W2039152055

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OpenAlex	10
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