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Synthesis and properties of novel energetic (cyano-NNO-azoxy)furazans Full article

Journal Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436
Output data Year: 2021, Volume: 31, Number: 6, Pages: 792-794 Pages count : 3 DOI: 10.1016/j.mencom.2021.11.007
Authors Leonov Nikita E. 1 , Sidorov Fedor M. 2,1 , Klenov Michael S. 1 , Churakov Aleksandr M. 1 , Strelenko Yurii A. 1 , Pivkina Alla N. 3 , Fedyanin Ivan V. 4,5 , Lempert David B. 6 , Kon'kova Tatiana S. 3 , Matyushin Yurii N. 3 , Tartakovsky Vladimir A. 1
Affiliations
1 N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
2 D. I. Mendeleev University of Chemical Technology of Russia, 125047 Moscow, Russian Federation
3 N. N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, 119991 Moscow, Russian Federation
4 A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991 Moscow, Russian Federation
5 G. V. Plekhanov Russian University of Economics, 117997 Moscow, Russian Federation
6 Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russian Federation

Abstract: Three novel energetic furazans with a cyano-NNO-azoxy group were synthesized using cyanamide and 2,2,2-tri- fluoro-N-(4-nitrosofurazan-3-yl)acetamide as the starting compounds. (Cyano-NNO-azoxy)furazans obtained display high experimental enthalpies of formation (+742 to +1073 kcal kg−1), good thermal stability (Tonset = 193–222 °C) and moderate mechanical sensitivity. These compounds may be of interest as energetic fillers in solid fuels for ramjet engines and in solid composite propellants.
Cite: Leonov N.E. , Sidorov F.M. , Klenov M.S. , Churakov A.M. , Strelenko Y.A. , Pivkina A.N. , Fedyanin I.V. , Lempert D.B. , Kon'kova T.S. , Matyushin Y.N. , Tartakovsky V.A.
Synthesis and properties of novel energetic (cyano-NNO-azoxy)furazans
Mendeleev Communications. 2021. V.31. N6. P.792-794. DOI: 10.1016/j.mencom.2021.11.007 WOS Scopus OpenAlex
Identifiers:
≡ Web of science: WOS:000731325700005
≡ Scopus: 2-s2.0-85120917590
≡ OpenAlex: W4206234843
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