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Alkene homologation via visible light promoted hydrophosphination using triphenylphosphonium triflate Full article

Journal Chemical Communications
ISSN: 1359-7345 , E-ISSN: 1364-548X
Output data Year: 2021, Volume: 57, Number: 6, Pages: 749-752 Pages count : 4 DOI: 10.1039/d0cc07025d
Authors Vitalij V Levin 1 , Alexander D Dilman 1
Affiliations
1 N. D. Zelinsky Institute of Organic Chemistry, Moscow 119991, Leninsky prosp. 47, Russian Federation

Abstract: A hydrophosphination reaction of alkenes with triphenylphosphonium triflate under photocatalytic conditions is described. The reaction is promoted by naphthalene-fused N-acylbenzimidazole and is believed to proceed through intermediate formation of a phosphinyl radical cation. The resulting phosphonium salts are directly involved in the Wittig reaction leading to homologated alkenes.
Cite: Vitalij V Levin , Alexander D Dilman
Alkene homologation via visible light promoted hydrophosphination using triphenylphosphonium triflate
Chemical Communications. 2021. V.57. N6. P.749-752. DOI: 10.1039/d0cc07025d WOS Scopus OpenAlex
Identifiers:
Web of science: WOS:000611726300010
Scopus: 2-s2.0-85100124148
OpenAlex: W3111766421
Citing:
DB Citing
OpenAlex 12
Scopus 9
Web of science 9
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