Alkene homologation via visible light promoted hydrophosphination using triphenylphosphonium triflate Full article
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Chemical Communications
ISSN: 1359-7345 , E-ISSN: 1364-548X |
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Output data | Year: 2021, Volume: 57, Number: 6, Pages: 749-752 Pages count : 4 DOI: 10.1039/d0cc07025d | ||
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Abstract:
A hydrophosphination reaction of alkenes with triphenylphosphonium triflate under photocatalytic conditions is described. The reaction is promoted by naphthalene-fused N-acylbenzimidazole and is believed to proceed through intermediate formation of a phosphinyl radical cation. The resulting phosphonium salts are directly involved in the Wittig reaction leading to homologated alkenes.
Cite:
Vitalij V Levin
, Alexander D Dilman
Alkene homologation via visible light promoted hydrophosphination using triphenylphosphonium triflate
Chemical Communications. 2021. V.57. N6. P.749-752. DOI: 10.1039/d0cc07025d WOS Scopus OpenAlex
Alkene homologation via visible light promoted hydrophosphination using triphenylphosphonium triflate
Chemical Communications. 2021. V.57. N6. P.749-752. DOI: 10.1039/d0cc07025d WOS Scopus OpenAlex
Identifiers:
Web of science: | WOS:000611726300010 |
Scopus: | 2-s2.0-85100124148 |
OpenAlex: | W3111766421 |