Thermal ring-opening reaction of N-polynitromethyl tetrazoles: facile generation of nitrilimines and their reactivity Научная публикация
| Журнал |
Tetrahedron
ISSN: 0040-4020 , E-ISSN: 1464-5416 |
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| Вых. Данные | Год: 2009, Том: 65, Номер: 17, Страницы: 3441-3445 Страниц : 5 DOI: 10.1016/j.tet.2009.02.032 | ||
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Реферат:
Thermal ring-opening reaction of N-(R-dinitromethyl)-5-nitrotetrazoles (R=NO2, F, Cl) yielded highly reactive N-(R-dinitromethyl)-nitrilimine intermediates under mild conditions. These species underwent facile and regiospecific reaction with nitriles and acetylenes to afford the corresponding nitrotriazoles and nitropyrazoles in 50–90% yields. Treatment of N-(chlorodinitromethyl)-5-nitrotetrazole with the excess of azide led to a unique compound with the molecular formula C2N14. Based on the analytical data, it was assigned a structure of diazidomethylenecarbonohydrazonic diazide.
Библиографическая ссылка:
Semenov V.V.
, Kanischev M.I.
, Shevelev S.A.
, Kiselyov A.S.
Thermal ring-opening reaction of N-polynitromethyl tetrazoles: facile generation of nitrilimines and their reactivity
Tetrahedron. 2009. V.65. N17. P.3441-3445. DOI: 10.1016/j.tet.2009.02.032 WOS Scopus OpenAlex
Thermal ring-opening reaction of N-polynitromethyl tetrazoles: facile generation of nitrilimines and their reactivity
Tetrahedron. 2009. V.65. N17. P.3441-3445. DOI: 10.1016/j.tet.2009.02.032 WOS Scopus OpenAlex
Идентификаторы БД:
| Web of science: | WOS:000265175100013 |
| Scopus: | 2-s2.0-62749178998 |
| OpenAlex: | W1979025404 |