The use of a new carboranylamidophosphite ligand in the asymmetric Pd-catalysed allylic alkylation in organic solvents and supercritical carbon dioxide

The use of a new carboranylamidophosphite ligand in the asymmetric Pd-catalysed allylic alkylation in organic solvents and supercritical carbon dioxide Full article

Journal

Journal of Organometallic Chemistry
ISSN: 1872-8561 , E-ISSN: 0022-328X

Output data

Year: 2009, Volume: 694, Number: 19, Pages: 3047-3049 Pages count : 3 DOI: 10.1016/j.jorganchem.2009.05.018

Authors

Lyubimov Sergey E. ¹ , Kuchurov Ilya V. ² , Vasil’ev Andrei A. ² , Tyutyunov Andrey A. ¹ , Kalinin Valery N. ¹ , Davankov Vadim A. ¹ , Zlotin Sergei G. ²

Affiliations

1	A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov Street 28, 119991 Moscow, Russia
2	N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prosp. 47, 119991 Moscow, Russia

A novel P-monodentate ligand based on carboranyl alcohol and (S)-2-(anilinomethyl)pyrrolidine provides high enantioselectivities (ee’s up to 95%) in the Pd-catalyzed allylic alkylation of (E)-1,3-diphenylallyl acetate. The first example of the Pd-catalysed allylic alkylation in supercritical carbon dioxide is also described.

Lyubimov S.E. , Kuchurov I.V. , Vasil’ev A.A. , Tyutyunov A.A. , Kalinin V.N. , Davankov V.A. , Zlotin S.G.
The use of a new carboranylamidophosphite ligand in the asymmetric Pd-catalysed allylic alkylation in organic solvents and supercritical carbon dioxide
Journal of Organometallic Chemistry. 2009. V.694. N19. P.3047-3049. DOI: 10.1016/j.jorganchem.2009.05.018 Scopus OpenAlex

Scopus:	2-s2.0-68049142276
OpenAlex:	W2024456054

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