Asymmetric allylic alkylation in supercritical carbon dioxide using P*-chiral diamidophosphite ligands

Asymmetric allylic alkylation in supercritical carbon dioxide using P*-chiral diamidophosphite ligands Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2010, Volume: 20, Number: 3, Pages: 143-144 Pages count : 2 DOI: 10.1016/j.mencom.2010.05.006

Authors

Lyubimov Sergey E. ¹ , Kuchurov Ilya V. ² , Vasil’ev Andrei A. ² , Zlotin Sergei G. ² , Davankov Vadim A. ¹

Affiliations

1	A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991 Moscow, Russian Federation
2	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation

P*-Chiral diamidophosphite ligands in the Pd-catalyzed allylic alkylation of (E)-1,3-diphenylallyl acetate in supercritical carbon dioxide provide enantioselectivities up to 90% ee. The catalytic performance is affected greatly by temperature, CO2 pressures and structure of catalysts.

Lyubimov S.E. , Kuchurov I.V. , Vasil’ev A.A. , Zlotin S.G. , Davankov V.A.
Asymmetric allylic alkylation in supercritical carbon dioxide using P*-chiral diamidophosphite ligands
Mendeleev Communications. 2010. V.20. N3. P.143-144. DOI: 10.1016/j.mencom.2010.05.006 Scopus OpenAlex

Scopus:	2-s2.0-77954200925
OpenAlex:	W2951857380

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