Synthesis of substituted dibenz[b,f]oxepines from 2,4,6-trinitrotoluene

Synthesis of substituted dibenz[b,f]oxepines from 2,4,6-trinitrotoluene Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2009, Volume: 58, Number: 2, Pages: 347-350 Pages count : 4 DOI: 10.1007/s11172-010-0014-6

Authors

Samet A.V. ¹ , Marshalkin V.N. ¹ , Lyssenko K.A. ² , Semenov V.V. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
2	A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russian Federation

1,3-Dinitro[b,f]dibenzoxepine undergoes nucleophilic substitution with O-and S-nucleophiles, the nitro group at position 1 (peri-nitro group) being selectively replaced. The factors responsible for the selectivity of the reaction are discussed.

Samet A.V. , Marshalkin V.N. , Lyssenko K.A. , Semenov V.V.
Synthesis of substituted dibenz[b,f]oxepines from 2,4,6-trinitrotoluene
Russian Chemical Bulletin. 2009. V.58. N2. P.347-350. DOI: 10.1007/s11172-010-0014-6 WOS Scopus OpenAlex

Web of science:	WOS:000275907000014
Scopus:	2-s2.0-77950265933
OpenAlex:	W1996659036

DB	Citing
OpenAlex	20
Scopus	16
Web of science	16