On the multiplicity of cathodically generated dianions of dinitrobenzenes

On the multiplicity of cathodically generated dianions of dinitrobenzenes Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2009, Volume: 58, Number: 1, Pages: 41-46 Pages count : 6 DOI: 10.1007/s11172-009-0006-6

Authors

Syroeshkin M.A. ¹ , Mikhailov M.N. ¹ , Mendkovich A.S. ¹ , Rusakov A.I. ²

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
2	P. G. Demidov Yaroslavl State University, Yaroslavl, Russian Federation

The results of DFT calculations indicate that the triplet state of 1, 3-dinitrobenzene, unlike that of other isomers, is thermodynamically more stable than the singlet one. This conclusion is confirmed by the comparison of the theoretical calculation results for the thermodynamics of formation of dinitrobenzene dianions with the experimental values obtained by cyclic voltammetry.

Syroeshkin M.A. , Mikhailov M.N. , Mendkovich A.S. , Rusakov A.I.
On the multiplicity of cathodically generated dianions of dinitrobenzenes
Russian Chemical Bulletin. 2009. V.58. N1. P.41-46. DOI: 10.1007/s11172-009-0006-6 WOS Scopus OpenAlex

≡ Web of science:	WOS:000276107500006
≡ Scopus:	2-s2.0-77649251691
≡ OpenAlex:	W2021590479