Synthesis of functionalized trimethylsilyl aminomethylphosphinates containing triethoxysilyl moieties

Synthesis of functionalized trimethylsilyl aminomethylphosphinates containing triethoxysilyl moieties Научная публикация

Журнал

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Вых. Данные

Год: 2023, Том: 72, Номер: 4, Страницы: 1088-1092 Страниц : 5 DOI: 10.1007/s11172-023-3875-3

Авторы

Prishchenko A.A. ¹ , Livantsov M.V. ¹ , Novikova O.P. ¹ , Livantsova L.I. ¹ , Baranin S.V. ² , Bubnov Yu.N. ^2,3

Организации

1	M. V. Lomonosov Moscow State University, Build. 3, 1 Leninskiye Gory, 119991, Moscow, Russian Federation
2	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation
3	A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Build. 1, 28 ul. Vavilova, 119334 Moscow, Russian Federation

A convenient synthesis of functionalized trimethylsilyl aminomethylphosphinates containing triethoxysilyl moieties was developed. Radical addition of bis(trimethylsiloxy)-phosphine to triethoxy(vinyl)silane proceeds regioselectively to afford a novel synthon, (2-triethoxysilylethyl)phosphonite, subsequent aminomethylation of which gives the target phosphinates.

Prishchenko A.A. , Livantsov M.V. , Novikova O.P. , Livantsova L.I. , Baranin S.V. , Bubnov Y.N.
Synthesis of functionalized trimethylsilyl aminomethylphosphinates containing triethoxysilyl moieties
Russian Chemical Bulletin. 2023. V.72. N4. P.1088-1092. DOI: 10.1007/s11172-023-3875-3 WOS Scopus OpenAlex

≡ Web of science:	WOS:000986557800030
≡ Scopus:	2-s2.0-85159138532
≡ OpenAlex:	W4376137893