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Aluminosilicate-supported cobalt catalysts in the Fischer-Tropsch synthesis Full article

Journal Petroleum Chemistry
ISSN: 0965-5441 , E-ISSN: 1555-6239
Output data Year: 2009, Volume: 49, Number: 4, Pages: 301-305 Pages count : 5 DOI: 10.1134/s0965544109040070
Authors Lapidus A.L. 1 , Pavlova V.A. 1 , Chin N.K. 2 , Eliseyev O.L. 1 , Gushchin V.V. 1 , Davydov P.E. 1
Affiliations
1 Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia
2 Gubkin State University of Oil and Gas, Moscow, Russia

Abstract: Cobalt catalysts supported on SIRAL aluminosilicates have been prepared and tested in hydrocarbon synthesis from CO and H2. It has been shown that the state of the cobalt metal on the catalyst surface is determined by both the cobalt content and the support nature, in particular, by the phase composition on its surface. The reaction rate on cobalt crystallites 3–6 nm in size is lower than that on 8–13-nm crystallites. It has been found that promotion with cerium oxide considerably increases the catalyst activity, although the selectivity for C5+ hydrocarbons slightly decreases.
Cite: Lapidus A.L. , Pavlova V.A. , Chin N.K. , Eliseyev O.L. , Gushchin V.V. , Davydov P.E.
Aluminosilicate-supported cobalt catalysts in the Fischer-Tropsch synthesis
Petroleum Chemistry. 2009. V.49. N4. P.301-305. DOI: 10.1134/s0965544109040070 WOS Scopus OpenAlex
Identifiers:
Web of science: WOS:000268499900007
Scopus: 2-s2.0-68249142000
OpenAlex: W2081524219
Citing:
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OpenAlex 6
Scopus 5
Web of science 5
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