Synthesis of 1,2,4,5,7,8-hexaoxonanes by iodine-catalyzed reactions of bis(1-hydroperoxycycloalkyl) peroxides with ketals

Synthesis of 1,2,4,5,7,8-hexaoxonanes by iodine-catalyzed reactions of bis(1-hydroperoxycycloalkyl) peroxides with ketals Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2009, Volume: 58, Number: 2, Pages: 335-338 Pages count : 4 DOI: 10.1007/s11172-010-0012-8

Authors

Terent’ev A.O. ¹ , Platonov M.M. ¹ , Krylov I.B. ¹ , Nikishin G.I. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

Iodine-catalyzed reactions of bis(1-hydroperoxycycloalkyl) peroxides with ketals give, via replacement of two alkoxy groups, the cyclic peroxides, 1,2,4,5,7,8-hexaoxonanes, in up to 82% yields. The cyclization is very sensitive to the solvent nature. Among MeCN, Et2O, THF, CHCl3, CH2Cl2, hexane, and MeOH, the best results were achieved with the first three solvents.

Terent’ev A.O. , Platonov M.M. , Krylov I.B. , Nikishin G.I.
Synthesis of 1,2,4,5,7,8-hexaoxonanes by iodine-catalyzed reactions of bis(1-hydroperoxycycloalkyl) peroxides with ketals
Russian Chemical Bulletin. 2009. V.58. N2. P.335-338. DOI: 10.1007/s11172-010-0012-8 WOS Scopus OpenAlex

≡ Web of science:	WOS:000275907000012
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