Facile Method for the Synthesis of Vicinal Azidoiodides by the Reaction of the NaN3–I2 System with Unsaturated Compounds

Facile Method for the Synthesis of Vicinal Azidoiodides by the Reaction of the NaN3–I2 System with Unsaturated Compounds Full article

Journal

Synthetic Communications
ISSN: 1532-2432 , E-ISSN: 0039-7911

Output data

Year: 2008, Volume: 38, Number: 21, Pages: 3797-3809 Pages count : 13 DOI: 10.1080/00397910802226572

Authors

Terent'ev Alexander O. ¹ , Krylov Igor B. ¹ , Kokorekin Vladimir A. ¹ , Nikishin Gennady I. ¹

Affiliations

1	a N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences , Moscow, Russian Federation

A facile and efficient method was developed for the synthesis of vicinal azidoiodides in 62–77% yields by the reaction of sodium azide and iodine with unsaturated compounds in methanol, aqueous methanol, or the water–methanol–tetrahydrofuran solvent system. The reaction in Et2O or CHCl3 produced only vicinal diiodides.

Terent'ev A.O. , Krylov I.B. , Kokorekin V.A. , Nikishin G.I.
Facile Method for the Synthesis of Vicinal Azidoiodides by the Reaction of the NaN3–I2 System with Unsaturated Compounds
Synthetic Communications. 2008. V.38. N21. P.3797-3809. DOI: 10.1080/00397910802226572 WOS Scopus OpenAlex

≡ Web of science:	WOS:000260209800020
≡ Scopus:	2-s2.0-54049123260
≡ OpenAlex:	W2094257859