The synthesis, structure, and electron density distribution in crystals of 4,5-dihydroxyimidazolidine-2-thiones

The synthesis, structure, and electron density distribution in crystals of 4,5-dihydroxyimidazolidine-2-thiones Научная публикация

Журнал

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Вых. Данные

Год: 2009, Том: 58, Номер: 7, Страницы: 1353-1360 Страниц : 8 DOI: 10.1007/s11172-009-0181-5

Авторы

Nelyubina Yu.V. ¹ , Gazieva G.A. ² , Baranov V.V. ² , Belyakov P.A. ² , Chizhov A.O. ² , Lyssenko K.A. ¹ , Kravchenko A.N. ²

Организации

1	A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation
2	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

1,3-H2-, 1,3-Me2-, and 1,3-Et2-4,5-Dihydroxyimidazolidine-2-thiones were synthesized and their structural peculiarities were studied. A comparative analysis of dihydroxyimidazolidine-2-thione and its carbonyl analog performed in the framework of detailed investigation of the electron density distribution in the corresponding crystals revealed the reason for different number and geometric parameters of the hydrogen bonds formed by the (thio)carbonyl groups in the crystals.

Nelyubina Y.V. , Gazieva G.A. , Baranov V.V. , Belyakov P.A. , Chizhov A.O. , Lyssenko K.A. , Kravchenko A.N.
The synthesis, structure, and electron density distribution in crystals of 4,5-dihydroxyimidazolidine-2-thiones
Russian Chemical Bulletin. 2009. V.58. N7. P.1353-1360. DOI: 10.1007/s11172-009-0181-5 WOS Scopus OpenAlex

≡ Web of science:	WOS:000278121700005
≡ Scopus:	2-s2.0-77955750189
≡ OpenAlex:	W1972969860