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Interrupted Nef and Meyer Reactions: A Growing Point for Diversity-Oriented Synthesis Based on Nitro Compounds Обзор

Журнал Molecules
ISSN: 1420-3049
Вых. Данные Год: 2023, Том: 28, Номер: 2, Номер статьи : 686, Страниц : 20 DOI: 10.3390/molecules28020686
Ключевые слова interrupted reactions; Nef reaction; Meyer reaction; nitro compounds; diversity-oriented synthesis; nucleophilic addition; iminium cations; nitrile oxides
Авторы Sukhorukov Alexey Yu. 1
Организации
1 N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prospect, 47, Moscow 119991, Russia

Реферат: The Nef reaction (nitro to carbonyl group conversion) and related Meyer reaction are among the key transformations of aliphatic nitro compounds. The interrupted versions of these reactions in which the normal pathway is redirected to a different end product by an external nucleophile are much less common, albeit these processes substantially increase the synthetic potential of nitro compounds. In this review, examples of interrupted Nef and Meyer reactions are summarized, and the prospects of this methodology in diversity-oriented organic synthesis are analyzed. The bibliography contains 90 references.
Библиографическая ссылка: Sukhorukov A.Y.
Interrupted Nef and Meyer Reactions: A Growing Point for Diversity-Oriented Synthesis Based on Nitro Compounds
Molecules. 2023. V.28. N2. 686 :1-20. DOI: 10.3390/molecules28020686 WOS Scopus OpenAlex
Идентификаторы БД:
Web of science: WOS:000922243100001
Scopus: 2-s2.0-85146722367
OpenAlex: W4315648115
Цитирование в БД:
БД Цитирований
OpenAlex 25
Web of science 22
Scopus 22
Альметрики: