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Oxidation of alkenes with hydrogen peroxide, catalyzed by boron trifluoride. Synthesis of vicinal methoxyalkanols Научная публикация

Журнал Russian Journal of General Chemistry
ISSN: 1070-3632 , E-ISSN: 1608-3350
Вых. Данные Год: 2008, Том: 78, Номер: 4, Страницы: 592-596 Страниц : 5 DOI: 10.1134/s1070363208040130
Авторы Terent’ev A.O. 1 , Boyarinova K.A. 1 , Nikishin G.I. 1
Организации
1 Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, Moscow, 119991, Russia

Реферат: In oxidation of alkenes with the BF3-H2O2 system, boron trifluoride induces transfer of available oxygen from hydrogen peroxide, accompanied by the formation of epoxides. The oxidation in methanol occurs as a one-pot two-step process involving epoxidation of the C=C bond followed by opening of the oxirane ring, with the formation of methoxyalkanols.
Библиографическая ссылка: Terent’ev A.O. , Boyarinova K.A. , Nikishin G.I.
Oxidation of alkenes with hydrogen peroxide, catalyzed by boron trifluoride. Synthesis of vicinal methoxyalkanols
Russian Journal of General Chemistry. 2008. V.78. N4. P.592-596. DOI: 10.1134/s1070363208040130 WOS Scopus OpenAlex
Идентификаторы БД:
≡ Web of science: WOS:000256176200013
≡ Scopus: 2-s2.0-44349177621
≡ OpenAlex: W2040358800
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