New Preparation of 1,2,4,5,7,8-Hexaoxonanes

New Preparation of 1,2,4,5,7,8-Hexaoxonanes Full article

Journal

Journal of Organic Chemistry
ISSN: 1520-6904 , E-ISSN: 0022-3263

Output data

Year: 2007, Volume: 72, Number: 19, Pages: 7237-7243 Pages count : 7 DOI: 10.1021/jo071072c

Authors

Terent'ev Alexander O. ¹ , Platonov Maxim M. ¹ , Sonneveld Eduard J. ² , Peschar Rene ² , Chernyshev Vladimir V. ^3,4 , Starikova Zoya A. ⁵ , Nikishin Gennady I. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation, Laboratory for Crystallography, Van't Hoff Institute for Molecular Sciences, University of Amsterdam, Valckenierstrasse 65, Amsterdam 1018 XE, The Netherlands, Department of Chemistry, Moscow State University, 119992 Moscow, Russian Federation, A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, 31 Leninsky prosp., 119991 Moscow, Russian Federation, and A. N....
2	Laboratory for Crystallography, Van't Hoff Institute for Molecular Sciences, University of Amsterdam, Valckenierstrasse 65, Amsterdam 1018 XE, The Netherlands
3	Department of Chemistry, Moscow State University, 119992 Moscow, Russian Federation
4	A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, 31 Leninsky prosp., 119991 Moscow, Russian Federation
5	A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991 Moscow, Russian Federation

A new versatile procedure was developed for the synthesis of 1,2,4,5,7,8-hexaoxonanes based on the Lewis acid catalyzed reaction of acetals with 1,1‘-dihydroperoxydicycloalkyl peroxides. The procedure substantially extends the structural diversity of these compounds and, in most cases, allows the synthesis of these compounds in higher yields (to 96%) and with higher selectivity. Complexation of hexaoxonane with chloroform was documented for the first time. The structures of several triperoxides were established by X-ray diffraction.

Terent'ev A.O. , Platonov M.M. , Sonneveld E.J. , Peschar R. , Chernyshev V.V. , Starikova Z.A. , Nikishin G.I.
New Preparation of 1,2,4,5,7,8-Hexaoxonanes
Journal of Organic Chemistry. 2007. V.72. N19. P.7237-7243. DOI: 10.1021/jo071072c WOS Scopus OpenAlex

≡ Web of science:	WOS:000249371200020
≡ Scopus:	2-s2.0-34548808549
≡ OpenAlex:	W2056131469