Facile Synthesis of E‐Diiodoalkenes: H2O2‐Activated Reaction of Alkynes with Iodine Научная публикация
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Synthetic Communications
ISSN: 1532-2432 , E-ISSN: 0039-7911 |
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| Вых. Данные | Год: 2007, Том: 37, Номер: 18, Страницы: 3151-3164 Страниц : 14 DOI: 10.1080/00397910701545171 | ||
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Реферат:
Hydrogen peroxide was found to activate iodine in the addition reaction with triple bonds. A facile and technologically straightforward procedure was developed for the synthesis of E‐diiodoalkenes based on the reaction of alkynes with an I2–H2O2 system in THF. Selective iodination of terminal and internal alkynes containing electron‐donating and electron‐withdrawing substituents afforded 16 E‐diiodoalkenes in yields up to 89%.
Библиографическая ссылка:
Terent'ev A.O.
, Borisov D.A.
, Krylov I.B.
, Nikishin G.I.
Facile Synthesis of E‐Diiodoalkenes: H2O2‐Activated Reaction of Alkynes with Iodine
Synthetic Communications. 2007. V.37. N18. P.3151-3164. DOI: 10.1080/00397910701545171 Scopus OpenAlex
Facile Synthesis of E‐Diiodoalkenes: H2O2‐Activated Reaction of Alkynes with Iodine
Synthetic Communications. 2007. V.37. N18. P.3151-3164. DOI: 10.1080/00397910701545171 Scopus OpenAlex
Идентификаторы БД:
| Scopus: | 2-s2.0-34548588336 |
| OpenAlex: | W2080235127 |