Stereoselective electrocatalytic transformation of malonate and alkylidenecyanoacetates into (E)-3-substituted 2-cyanocyclopropane-1,1,2-tricarboxylates

Stereoselective electrocatalytic transformation of malonate and alkylidenecyanoacetates into (E)-3-substituted 2-cyanocyclopropane-1,1,2-tricarboxylates Full article

Journal

Tetrahedron
ISSN: 0040-4020 , E-ISSN: 1464-5416

Output data

Year: 2006, Volume: 62, Number: 17, Pages: 3989-3996 Pages count : 8 DOI: 10.1016/j.tet.2006.02.027

Authors

Elinson Michail N. ¹ , Feducovich Sergey K. ¹ , Starikova Zoya A. ² , Vereshchagin Anatolii N. ¹ , Belyakov Pavel A. ¹ , Nikishin Gennady I. ¹

Affiliations

1	N.D. Zelinsky Institute of Organic Chemistry, Leninsky prospect 47, 119991 Moscow, Russian Federation
2	A.N. Nesmeyanov Institute of Organoelement compounds, ul. Vavilova 28, 119991 Moscow, Russian Federation

Electrolysis of malonate and alkylidenecyanoacetates in alcohols in an undivided cell in the presence of NaBr results in stereoselective formation of (E)-3-substituted 2-cyanocyclopropane-1,1,2-tricarboxylates in 75–90% yields.

Elinson M.N. , Feducovich S.K. , Starikova Z.A. , Vereshchagin A.N. , Belyakov P.A. , Nikishin G.I.
Stereoselective electrocatalytic transformation of malonate and alkylidenecyanoacetates into (E)-3-substituted 2-cyanocyclopropane-1,1,2-tricarboxylates
Tetrahedron. 2006. V.62. N17. P.3989-3996. DOI: 10.1016/j.tet.2006.02.027 WOS Scopus OpenAlex

Web of science:	WOS:000236814800006
Scopus:	2-s2.0-33645960943
OpenAlex:	W2066341738

DB	Citing
OpenAlex	40
Scopus	40
Web of science	42