Organophotoredox-Catalyzed Reductive Tetrafluoroalkylation of Alkenes

Organophotoredox-Catalyzed Reductive Tetrafluoroalkylation of Alkenes Full article

Journal

Journal of Organic Chemistry
ISSN: 1520-6904 , E-ISSN: 0022-3263

Output data

Year: 2023, Volume: 88, Number: 10, Pages: 6523-6531 Pages count : 9 DOI: 10.1021/acs.joc.2c00712

Authors

Kostromitin Vladislav S. ^1,2 , Levin Vitalij V. ² , Dilman Alexander D. ²

Affiliations

1	Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory 1-3, 119991 Moscow, Russian Federation
2	N. D. Zelinsky Institute of Organic Chemistry, Leninsky prosp. 47, 119991 Moscow, Russian Federation

A method for the hydroperfluoroalkylation of alkenes with 1,2-dibromotetrafluoroethane leading to tetrafluorinated bromides is described. The reaction is conveniently performed under blue light irradiation using an organic photocatalyst and ascorbic acid as a reducing agent. Primary products can be further functionalized via radical pathways affording various tetrafluorinated compounds.

Kostromitin V.S. , Levin V.V. , Dilman A.D.
Organophotoredox-Catalyzed Reductive Tetrafluoroalkylation of Alkenes
Journal of Organic Chemistry. 2023. V.88. N10. P.6523-6531. DOI: 10.1021/acs.joc.2c00712 WOS Scopus OpenAlex

Web of science:	WOS:000821352500001
Scopus:	2-s2.0-85131037363
OpenAlex:	W4280618194

DB	Citing
OpenAlex	11
Scopus	10
Web of science	8