Gas phase kinetic and theoretical studies of reactions of germylenes and dimethylstannylene

Gas phase kinetic and theoretical studies of reactions of germylenes and dimethylstannylene Review

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2005, Volume: 54, Number: 3, Pages: 483-511 Pages count : 29 DOI: 10.1007/s11172-005-0285-5

Authors

Boganov S.E. ¹ , Egorov M.P. ¹ , Faustov V.I. ¹ , Krylov I.V. ¹ , Nefedov O.M. ¹ , Becerra R. ² , Walsh R. ³

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prospekt, 119991, Moscow, Russian Federation
2	Instituto de Quimica Fisica “Rocasolano”, C. S. I. C., C/Serrano 119, 28006, Madrid, Spain
3	Department of Chemistry, University of Reading, Whiteknights, P. O. Box 224, Reading, RG6 6AD, UK

The results of time resolved gas phase studies of labile germylenes (GeH2 and GeMe2) and dimethylstannylene (SnMe2) reactions reported to date are considered together with data of quantum-chemical investigations of the potential energy surfaces of these systems. Reaction mechanisms are discussed. A comparison of reactivity in the series of carbene analogs, ER2 (E = Si, Ge, Sn, R = H, Me), is made.

Boganov S.E. , Egorov M.P. , Faustov V.I. , Krylov I.V. , Nefedov O.M. , Becerra R. , Walsh R.
Gas phase kinetic and theoretical studies of reactions of germylenes and dimethylstannylene
Russian Chemical Bulletin. 2005. V.54. N3. P.483-511. DOI: 10.1007/s11172-005-0285-5 WOS Scopus OpenAlex

≡ Web of science:	WOS:000232042300001
≡ Scopus:	2-s2.0-25144491158
≡ OpenAlex:	W2016246002