Synthesis of novel derivatives of closo‐dodecaborate anion with azido group at the terminal position of the spacer

Synthesis of novel derivatives of closo‐dodecaborate anion with azido group at the terminal position of the spacer Full article

Journal

Applied Organometallic Chemistry
ISSN: 0268-2605 , E-ISSN: 1099-0739

Output data

Year: 2007, Volume: 21, Number: 2, Pages: 98-100 Pages count : 3 DOI: 10.1002/aoc.1151

Authors

Orlova Anna V. ¹ , Kondakov Nikolay N. ¹ , Kimel Boris G. ¹ , Kononov Leonid O. ¹ , Kononova Elena G. ² , Sivaev Igor B. ² , Bregadze Vladimir I. ²

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry of the RAS, Leninsky prospect, 47, 119991, Moscow, Russian Federation
2	A. N. Nesmeyanov Institute of Organo-Element Compounds of the RAS, Vavilova, 28, 119991, Moscow, Russian Federation

Two novel azido-derivatives of closo-dodecaborate anion with hydrophobic and hydrophilic spacers were prepared by reaction of tetrabutylammonium azide with cyclic oxonium derivatives of the closo-dodecaborate anion. The compounds prepared can be regarded as precursors of derivatives of closo-dodecaborate anion with amino group at the terminal position of a spacer or as building blocks for ‘click chemistry’, which are useful for preparation of various conjugates with targeting molecules. A concentration dependence of the 11B NMR spectra of functionalized derivatives of closo-dodecaborate anion was discovered, which is of great importance for analytical purposes. Copyright © 2006 John Wiley & Sons, Ltd.

Orlova A.V. , Kondakov N.N. , Kimel B.G. , Kononov L.O. , Kononova E.G. , Sivaev I.B. , Bregadze V.I.
Synthesis of novel derivatives of closo‐dodecaborate anion with azido group at the terminal position of the spacer
Applied Organometallic Chemistry. 2007. V.21. N2. P.98-100. DOI: 10.1002/aoc.1151 WOS Scopus OpenAlex

Web of science:	WOS:000243980800007
Scopus:	2-s2.0-33846682342
OpenAlex:	W1996266494

DB	Citing
OpenAlex	37
Scopus	38
Web of science	33