Nickel-catalyzed addition of benzenethiol to alkynes: Formation of carbon-sulfur and carbon-carbon bonds

Nickel-catalyzed addition of benzenethiol to alkynes: Formation of carbon-sulfur and carbon-carbon bonds Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2006, Volume: 55, Number: 11, Pages: 2109-2113 Pages count : 5 DOI: 10.1007/s11172-006-0557-8

Authors

Ananikov V.P. ¹ , Zalesskiy S.S. ¹ , Orlov N.V. ¹ , Beletskaya I.P. ²

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation
2	M. V. Lomonosov Moscow State University, 1 Leninskie gory, 119992, Moscow, Russian Federation

Nickel-catalyzed addition of benzenethiol to alkynes leads to alkenyl and dienyl sulfides; the direction of the process can be controlled by varying the PhSH/alkyne ratio. An advanced procedure, which ensures higher yields of 2-phenylsulfanylalkenes, includes gradual addition of alkyne to the other reactants. The structures of conjugated dienyl sulfides formed in the reaction were determined by 2D NMR spectroscopy.

Ananikov V.P. , Zalesskiy S.S. , Orlov N.V. , Beletskaya I.P.
Nickel-catalyzed addition of benzenethiol to alkynes: Formation of carbon-sulfur and carbon-carbon bonds
Russian Chemical Bulletin. 2006. V.55. N11. P.2109-2113. DOI: 10.1007/s11172-006-0557-8 WOS Scopus OpenAlex

Web of science:	WOS:000245501600030
Scopus:	2-s2.0-34247170535
OpenAlex:	W2952046525

DB	Citing
OpenAlex	28
Scopus	23
Web of science	25