A new oxidation process. Transformation of gem-bishydroperoxides into esters

A new oxidation process. Transformation of gem-bishydroperoxides into esters Full article

Journal

Open Chemistry
ISSN: 2391-5420

Output data

Year: 2006, Volume: 4, Number: 2, Pages: 207-215 Pages count : 9 DOI: 10.2478/s11532-006-0012-6

Authors

Terent’ev Alexander ¹ , Platonov Maxim ¹ , Kutkin Alexander ¹

Affiliations

1	N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991, Leninsky Prospect 47, Moscow, Russia

A new oxidation process has been found where α,ω-dicarboxylic acid esters and ωhydroxycarboxylic acid esters are formed on heating gem-bishydroperoxides in alcohol in the presence of BF3·Et2O. By addition of H2O2 to this reaction α,ω-dicarboxylic acid esters are formed almost selectively.

Terent’ev A. , Platonov M. , Kutkin A.
A new oxidation process. Transformation of gem-bishydroperoxides into esters
Open Chemistry. 2006. V.4. N2. P.207-215. DOI: 10.2478/s11532-006-0012-6 WOS Scopus OpenAlex

≡ Web of science:	WOS:000239340200001
≡ Scopus:	2-s2.0-33751018852
≡ OpenAlex:	W2022666445