Synthesis of Pentafluorophenylmethylamines via Silicon Mannich Reaction Full article
Journal |
Organic Letters
ISSN: 1523-7060 , E-ISSN: 1523-7052 |
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Output data | Year: 2005, Volume: 7, Number: 14, Pages: 2913-2915 Pages count : 3 DOI: 10.1021/ol050845l | ||||
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Abstract:
The three-component coupling of aldehydes, secondary amines, and methoxytris(pentafluorophenyl)silane, MeOSi(C6F5)3, affording pentafluorophenylmethylamines has been described. The generation of the five-coordinate silicate intermediate is believed to be the key feature responsible for the efficiency of the reaction.
Cite:
Dilman A.D.
, Belyakov P.A.
, Korlyukov A.A.
, Struchkova M.I.
, Tartakovsky V.A.
Synthesis of Pentafluorophenylmethylamines via Silicon Mannich Reaction
Organic Letters. 2005. V.7. N14. P.2913-2915. DOI: 10.1021/ol050845l Scopus OpenAlex
Synthesis of Pentafluorophenylmethylamines via Silicon Mannich Reaction
Organic Letters. 2005. V.7. N14. P.2913-2915. DOI: 10.1021/ol050845l Scopus OpenAlex
Identifiers:
Scopus: | 2-s2.0-22244493902 |
OpenAlex: | W2950839881 |