ortho-Dialkylamino arylboranes as efficient reagents for difluorocarbene trapping

ortho-Dialkylamino arylboranes as efficient reagents for difluorocarbene trapping Full article

Journal

Chemical Communications
ISSN: 1359-7345 , E-ISSN: 1364-548X

Output data

Year: 2020, Volume: 56, Number: 52, Pages: 7140-7142 Pages count : 3 DOI: 10.1039/d0cc02567d

Authors

Ilin Egor A ^1,2 , Smirnov Vladimir O ¹ , Volodin Alexander D ³ , Korlyukov Alexander A ³ , Dilman Alexander D ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Leninsky prosp. 47, 119991 Moscow, Russian Federation
2	Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory 1-3, 119991 Moscow, Russian Federation
3	A. N. Nesmeyanov Institute of Organoelement Compounds, Vavilov str. 28, 119991 Moscow, Russian Federation

Compounds bearing ortho-oriented dialkylamino and boryl groups can serve as efficient reagents to trap difluorocarbene leading to zwitterionic ammonium borates featuring N-CF2-B fragments. The reagents are shelf-stable and can be used as mechanistic probes for reactions proceeding via difluorocarbene.

Ilin E.A. , Smirnov V.O. , Volodin A.D. , Korlyukov A.A. , Dilman A.D.
ortho-Dialkylamino arylboranes as efficient reagents for difluorocarbene trapping
Chemical Communications. 2020. V.56. N52. P.7140-7142. DOI: 10.1039/d0cc02567d WOS Scopus OpenAlex

Web of science:	WOS:000544483800013
Scopus:	2-s2.0-85087465551
OpenAlex:	W3026650874

DB	Citing
OpenAlex	20
Scopus	21
Web of science	20