Chloride ion promoted nucleophilic pentafluorophenylation of imines | Sciact

Chloride ion promoted nucleophilic pentafluorophenylation of imines Научная публикация

Журнал

Tetrahedron Letters
ISSN: 0040-4039 , E-ISSN: 1873-3581

Вых. Данные

Год: 2006, Том: 47, Номер: 50, Страницы: 8959-8963 Страниц : 5 DOI: 10.1016/j.tetlet.2006.10.019

Авторы

Levin Vitalij V. ¹ , Dilman Alexander D. ¹ , Belyakov Pavel A. ¹ , Struchkova Marina I. ¹ , Tartakovsky Vladimir A. ¹

Организации

1	N.D. Zelinsky Institute of Organic Chemistry, 119991 Moscow, Leninsky prosp. 47, Russian Federation

Nucleophilic addition of the pentafluorophenyl group from (C6F5)3SiF to non-activated imines affording α-C6F5-substituted secondary amines in high yield has been described. The reaction proceeds via simultaneous activation of imines and the silane reagent by means of a proton and chloride ion, respectively.

Levin V.V. , Dilman A.D. , Belyakov P.A. , Struchkova M.I. , Tartakovsky V.A.
Chloride ion promoted nucleophilic pentafluorophenylation of imines
Tetrahedron Letters. 2006. V.47. N50. P.8959-8963. DOI: 10.1016/j.tetlet.2006.10.019 WOS Scopus OpenAlex

≡ Web of science:	WOS:000242483300034
≡ Scopus:	2-s2.0-33750621348
≡ OpenAlex:	W2165741458