Novel synthesis of α-nitroalkenes from nitroalkanes via halogenation of intermediate N,N-bis(silyloxy)enamines Научная публикация
Журнал |
Tetrahedron Letters
ISSN: 0040-4039 , E-ISSN: 1873-3581 |
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Вых. Данные | Год: 2005, Том: 46, Номер: 31, Страницы: 5203-5205 Страниц : 3 DOI: 10.1016/j.tetlet.2005.05.113 | ||
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Реферат:
An approach to conjugated nitroalkenes via oxidation of N,N-bis(silyloxy)enamines with bromine or iodine in the presence of tetra-n-butylammonium acetate is described. The acetate ion plays a key role by acting as a mild desilylating reagent. This new strategy allows the synthesis of α-nitroalkenes from the corresponding nitroalkanes.
Библиографическая ссылка:
Kunetsky R.A.
, Dilman A.D.
, Struchkova M.I.
, Tartakovsky V.A.
, Ioffe S.L.
Novel synthesis of α-nitroalkenes from nitroalkanes via halogenation of intermediate N,N-bis(silyloxy)enamines
Tetrahedron Letters. 2005. V.46. N31. P.5203-5205. DOI: 10.1016/j.tetlet.2005.05.113 Scopus OpenAlex
Novel synthesis of α-nitroalkenes from nitroalkanes via halogenation of intermediate N,N-bis(silyloxy)enamines
Tetrahedron Letters. 2005. V.46. N31. P.5203-5205. DOI: 10.1016/j.tetlet.2005.05.113 Scopus OpenAlex
Идентификаторы БД:
Scopus: | 2-s2.0-21344434760 |
OpenAlex: | W2154821630 |