Stereoselective electrocatalytic transformations of malononitrile and aromatic aldehydes into (1R,5S,6R)*-4,4-dialkoxy-2-amino-6-aryl-1,5-dicyano-3-azabicyclo[3.1.0]hex-2-enes

Stereoselective electrocatalytic transformations of malononitrile and aromatic aldehydes into (1R,5S,6R)*-4,4-dialkoxy-2-amino-6-aryl-1,5-dicyano-3-azabicyclo[3.1.0]hex-2-enes Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2005, Volume: 54, Number: 3, Pages: 673-677 Pages count : 5 DOI: 10.1007/s11172-005-0304-6

Authors

Elinson M.N. ¹ , Feducovich .K. ¹ , Zaimovskaya T.A. ² , Vereshchagin A.N. ¹ , Nikishin G.I. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
2	A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation

Electrolysis of aromatic aldehydes and malononitrile in alcohols in an undivided cell in the presence of a NaBr-NaOAc mediatory system stereoselectively gave bicyclic compounds containing the cyclopropane and pyrroline fragments in 60 to 70% yields. In the bicyclic products, the benzene and pyrroline rings are on different sides of the cyclopropane ring.

Elinson M.N. , Feducovich K. , Zaimovskaya T.A. , Vereshchagin A.N. , Nikishin G.I.
Stereoselective electrocatalytic transformations of malononitrile and aromatic aldehydes into (1R,5S,6R)*-4,4-dialkoxy-2-amino-6-aryl-1,5-dicyano-3-azabicyclo[3.1.0]hex-2-enes
Russian Chemical Bulletin. 2005. V.54. N3. P.673-677. DOI: 10.1007/s11172-005-0304-6 Scopus OpenAlex

Scopus:	2-s2.0-25144495602
OpenAlex:	W2951736562

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