Synthesis and structural characterization of carbon-centered tris(pentafluorophenyl)silyl derivatives

Synthesis and structural characterization of carbon-centered tris(pentafluorophenyl)silyl derivatives Full article

Journal

Journal of Organometallic Chemistry
ISSN: 1872-8561 , E-ISSN: 0022-328X

Output data

Year: 2005, Volume: 690, Number: 16, Pages: 3680-3689 Pages count : 10 DOI: 10.1016/j.jorganchem.2005.04.058

Authors

Dilman Alexander D. ¹ , Arkhipov Dmitry E. ² , Korlyukov Alexander A. ³ , Ananikov Valentine P. ¹ , Danilenko Vitalij M. ² , Tartakovsky Vladimir A. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, 119991 Moscow, Leninsky prosp. 47, Russian Federation
2	Moscow Chemical Lyceum, 109033 Moscow, Tamozhennyi pr. 4, Russian Federation
3	A. N. Nesmeyanov Institute of Organoelement Compounds, 119991 Moscow, Vavilov str. 28, Russian Federation

A general method for the synthesis of carbon-centered tris(pentafluorophenyl)silyl derivatives (RSi(C6F5)3) by reaction of trichlorosilanes (RSiCl3) with pentafluorophenylmagnesium bromide was described. The crystal structures of obtained compounds were studied by X-ray diffraction analysis (7 structures). The peculiarities of crystal packing were analyzed by means of DFT calculations.

Dilman A.D. , Arkhipov D.E. , Korlyukov A.A. , Ananikov V.P. , Danilenko V.M. , Tartakovsky V.A.
Synthesis and structural characterization of carbon-centered tris(pentafluorophenyl)silyl derivatives
Journal of Organometallic Chemistry. 2005. V.690. N16. P.3680-3689. DOI: 10.1016/j.jorganchem.2005.04.058 Scopus OpenAlex

Scopus:	2-s2.0-23844436309
OpenAlex:	W1989045437

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OpenAlex	11
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